Microsoft released some free chapters of the new Moving to TFS 2010 book. This book will help professional developers move from previous versions of Visual Studio. It will cover the features of Visual Studio 2010 through an application. It will go through a lot of the exciting new language features and new versions of the most popular technologies without putting the emphasis on the technologies themselves. It will instead put the emphasis on how you would get to those new tools and features from Visual Studio 2010.
Download some free chapters: http://www.microsoft.com/downloads/details.aspx?displaylang=en&FamilyID=560a5365-5c62-488a-91ed-a779e0e33ac4